-κC]iridium hexafL
[4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
CAS: 1072067-44-7
Molecular Formula: C40H36F10IrN4P
-κC]iridium hexafL - Names and Identifiers
| Name | [4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate |
| Synonyms | -κC]iridium hexafL Ir[dFppy]2(dtbbpy)PF6 (Ir[dFppy]2(dtbpy))PF6 [4,4'-Bis(1,1-dimethyL )-2,2'-bipyridine-κN,κN]bis[3,5-difL [2,2'-bis (4-tert-butylpyridine)] bis [2- (2,4-difluorophenyl) pyridine] iridium (III) hexafluorophosphate [4,4'-Bis(1,1-dimethylethyl)-2,2'-bipyridine-κN,κN]bis[3,5-difluoro-2-(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate |
| CAS | 1072067-44-7 |
-κC]iridium hexafL - Physico-chemical Properties
| Molecular Formula | C40H36F10IrN4P |
| Molar Mass | 985.93 |
| Melting Point | >300°C |
| Appearance | powder or crystals |
| Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
-κC]iridium hexafL - Introduction
[4,4 '-BIS (1,1-dimethylethyl)-2,2'-BIPYRIDINE-κN, κN] BIS [3,5-DIFLUORO -2-(2-PYRIDINYL-κN) PHYL-κC] iridium hexafluorophosphate (abbreviated as IR (DFPPY) (DTBBPY) PF is an electroluminescent material commonly used in LED.
The following are some of its properties and characteristics:
-Chemical formula: C "H" F "IrN" P"
-Molecular weight: 1054.84g/mol
-Appearance: red or orange crystal powder
-Solubility: Ir(dfppy)₂(dtbbpy) PFⅨ is soluble in common solvents such as dimethyl sulfoxide and chloroform.
Use:
-Photoluminescent material: Ir(dfppy)₂(dtbbpy)PF is commonly used in the light-emitting layer of OLEDs, and its carriers in the light-emitting layer recombine to generate visible light.
-Optoelectronic devices: Due to its optoelectronic characteristics, it can be used in optoelectronic devices such as solar cells and organic lasers.
Preparation Method:
The preparation method of Ir(dfppy) member (dtbbpy)PF generally involves the following steps:
1. synthesis of intermediates: first synthesis of [4,4 '-bis (1,1-dimethylethyl)-2,2'-bipyridine] dibromide and 2-bromo -3,5-difluoro-pyridine.
2. synthesis of precursor complex: the intermediate is reacted with cyano [2,2 '-bipyridine] and fluorophenyl ligand to form [4,4'-bis (1,1-dimethylethyl)-2,2 '-bipyridine-k N,k N] bis [3, 5-Difluoro-2-(2-pyridyl-k N) phenyl-k C] iridium (III) complex.
3. Hexafluorophosphate exchange: Finally, the precursor complex is treated with a hexafluorophosphate solution (such as hexafluorophosphoric acid or ammonium hexafluorophosphate) to form Ir(dfppy)₂(dtbbpy)PF.
Safety Information:
The safety information of Ir(dfppy) member (dtbbpy)PF is limited. Therefore, appropriate safety measures need to be taken during operation and handling. Avoid inhaling, swallowing or touching the substance, and pay attention to the use of protective gloves, safety glasses and appropriate ventilation conditions. During use, please follow the correct laboratory procedures and safe operation guidelines. If you have any questions or need further information, please refer to the safety data sheet of the compound or consult a chemical expert.
The following are some of its properties and characteristics:
-Chemical formula: C "H" F "IrN" P"
-Molecular weight: 1054.84g/mol
-Appearance: red or orange crystal powder
-Solubility: Ir(dfppy)₂(dtbbpy) PFⅨ is soluble in common solvents such as dimethyl sulfoxide and chloroform.
Use:
-Photoluminescent material: Ir(dfppy)₂(dtbbpy)PF is commonly used in the light-emitting layer of OLEDs, and its carriers in the light-emitting layer recombine to generate visible light.
-Optoelectronic devices: Due to its optoelectronic characteristics, it can be used in optoelectronic devices such as solar cells and organic lasers.
Preparation Method:
The preparation method of Ir(dfppy) member (dtbbpy)PF generally involves the following steps:
1. synthesis of intermediates: first synthesis of [4,4 '-bis (1,1-dimethylethyl)-2,2'-bipyridine] dibromide and 2-bromo -3,5-difluoro-pyridine.
2. synthesis of precursor complex: the intermediate is reacted with cyano [2,2 '-bipyridine] and fluorophenyl ligand to form [4,4'-bis (1,1-dimethylethyl)-2,2 '-bipyridine-k N,k N] bis [3, 5-Difluoro-2-(2-pyridyl-k N) phenyl-k C] iridium (III) complex.
3. Hexafluorophosphate exchange: Finally, the precursor complex is treated with a hexafluorophosphate solution (such as hexafluorophosphoric acid or ammonium hexafluorophosphate) to form Ir(dfppy)₂(dtbbpy)PF.
Safety Information:
The safety information of Ir(dfppy) member (dtbbpy)PF is limited. Therefore, appropriate safety measures need to be taken during operation and handling. Avoid inhaling, swallowing or touching the substance, and pay attention to the use of protective gloves, safety glasses and appropriate ventilation conditions. During use, please follow the correct laboratory procedures and safe operation guidelines. If you have any questions or need further information, please refer to the safety data sheet of the compound or consult a chemical expert.
Last Update：2024-04-10 22:29:15
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